THE 1ST EXAMPLES OF INSERTION OF SNCL2 INTO THE MN-CL AND RE-CL BONDS OF OCTAHEDRAL COMPLEXES - X-RAY STRUCTURE OF [MN(CO)3(SNCL3)(S2CPCY3)]BULLET-CH2CL2

被引：11

作者：

ALVAREZ, B

MIGUEL, D

PEREZMARTINEZ, JA

RIERA, V

GARCIAGRANDA, S

机构：

[1] UNIV OVIEDO,DEPT QUIM ORGANOMET,E-33071 OVIEDO,SPAIN

[2] UNIV OVIEDO,DEPT QUIM FIS & ANALIT,E-33071 OVIEDO,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80082-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Compounds fac-[M(CO)3(S2CPR3)Cl] (M = Mn or Re; R = cyclohexyl or isopropyl) react with SnCl2 in tetrahydrofuran (THF) within 30 min to give trichlorostannyl complexes fac-[M(CO)3(S2CPR3)(SnCl3)], these being the first examples of a direct insertion of SnCl2 into Mn-Cl or Re-Cl bonds of octahedral carbonyl complexes. The structure of the trichlorostannyl derivative of manganese (R = cyclohexyl) has been determined by X-ray diffraction. Several experimental facts suggest that the facile insertion of SnCl2 in the starting fac-[M(CO)3(S2CPR3)Cl] complexes should be attributed to the presence of the S2CPR3 ligands.

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页码：C33 / C36

页数：4

相关论文

共 14 条

[1]

BEURSKENS PT, 1982, CONFORMATION BIOL, P389

[2] REACTIVITY OF METAL-METAL BONDS .2. TIN-MANGANESE BOND [J].

CLARK, HC ;

TSAI, JH .

INORGANIC CHEMISTRY, 1966, 5 (08) :1407-&

[3] PREPARATION AND PROPERTIES OF SOME MIXED METAL CARBONYL COMPOUNDS .1. COMPOUNDS CONTAINING A GROUP IV METAL AND MANGANESE OR IRON [J].

GORSICH, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (13) :2486-&

[4] HETERONUCLEAR METAL ATOM CLUSTERS OF THE TYPES X4-N [SNM(CO)4P(C6H5)3]N AND M2(CO)8 [MU-SN(X)M(CO)4P(C6H5)3]2 BY REACTION OF SNX2 WITH M2(CO)8 [P(C6H5)3]2 (X = HALOGENE-M = MN, RE-N = 2,3) [J].

HAUPT, HJ ;

BALSAA, P ;

SCHWAB, B ;

FLORKE, U ;

PREUT, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 513 (06) :22-34

[5] TRANSITION-METAL TIN CHEMISTRY [J].

HOLT, MS ;

WILSON, WL ;

NELSON, JH .

CHEMICAL REVIEWS, 1989, 89 (01) :11-49

[6] ORGANOMETALLIC COMPOUNDS WITH METAL-METAL BONDS .4. PENTACARBONYLMANGANESE AND PENTACARBONYLRHENIUM DERIVATIVES OF SILICON GERMANIUM TIN AND LEAD . PREPARATION AND INFRARED AND NUCLEAR MAGNETIC RESONANCE STUDIES [J].

JETZ, W ;

SIMONS, PB ;

THOMPSON, JA ;

GRAHAM, WAG .

INORGANIC CHEMISTRY, 1966, 5 (12) :2217-&

[7] SUBVALENT GROUP-4B METAL ALKYLS AND AMIDES .7. TRANSITION-METAL CHEMISTRY OF METAL(II) BIS(TRIMETHYLSILYL)AMIDES GE'[N(SIME3)2]2, SN'[N(SIME3)2]2, PB'[N(SIME3)2]2 [J].

LAPPERT, MF ;

POWER, PP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (01) :51-57

[8] MANGANESE(I) COMPLEXES WITH (TRICYCLOHEXYLPHOSPHONIO)DITHIOCARBOXYLATE AS CHELATE AND UNIDENTATE LIGAND - X-RAY CRYSTAL-STRUCTURE OF FAC-[MN(CO)3(S2CP(C6H11)3)2]CLO4.H2O [J].

MIGUEL, D ;

RIERA, V ;

MIGUEL, JA ;

BOIS, C ;

PHILOCHELEVISALLES, M ;

JEANNIN, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (12) :2875-2880

[9] MANGANESE COMPLEXES WITH S2CPET3 LIGANDS - X-RAY CRYSTAL-STRUCTURES OF CIS-TRANS-[MN(CO)2(PET3)2(S2CPET3)]CLO4 AND CIS-TRANS-[MN(CO)2(PET3)2-(S2CH)] [J].

MIGUEL, D ;

RIERA, V ;

MIGUEL, JA ;

DIEGO, F ;

BOIS, C ;

JEANNIN, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (09) :2719-2727

[10] RING-OPENING AND CLOSING IN (CO)N(L)MNI COMPLEXES WHERE L=S2CPCY3 OR DIPHOSPHINE - NOVEL COMPLEXES CONTAINING THE MN(MU-L)AUC6F5 ENTITY WHERE L=S2CPCY3 OR DPPM [J].

MIGUEL, D ;

RIERA, V ;

MIGUEL, JA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (1-2) :127-136