ENANTIOSELECTIVE CATALYSIS .94. THE DIPHENYL EFFECT IN THE ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH DIPHENYLSILANE USING RH/5,5-DIPHENYL-2-(2-PYRIDINYL)OXAZOLINE CATALYSTS

被引：34
作者：
BRUNNER, H
HENRICHS, C
机构：
[1] Institut für Anorganische Chemie, Universität Regensburg
来源：
TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 03期
关键词：
D O I：
10.1016/0957-4166(95)00052-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The 5,5-diphenyl-2-(2-pyridinyl)oxazolines 2a-e give ee values 9.6 - 34.2 % higher than their unsubstituted counterparts 1a-e in the Rh-catalyzed enantioselective hydrosilylation of acetophenone with diphenylsilane.
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页码：653 / 656
页数：4
相关论文
共 21 条
[1]   ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH RHODIUM OXAZOLINES CATALYSTS [J].
BALAVOINE, G ;
CLINET, JC ;
LELLOUCHE, I .
TETRAHEDRON LETTERS, 1989, 30 (38) :5141-5144
[2]   ASYMMETRICAL CATALYSTS .32. ENANTIOSELECTIVE PHENYLATION OF CIS-CYCLOHEXANE-1,2-DIOL AND MESO-BUTANE-2,3-DIOL [J].
BRUNNER, H ;
OBERMANN, U ;
WIMMER, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 316 (1-2) :C1-C3
[3]   ASYMMETRIC CATALYSIS .45. ENANTIOSELECTIVE HYDROSILYLATION OF KETONES WITH [RH(COD)CL]2/PYRIDINYLOXAZOLINE CATALYSTS [J].
BRUNNER, H ;
OBERMANN, U .
CHEMISCHE BERICHTE-RECUEIL, 1989, 122 (03) :499-507
[4]   ENANTIOSELECTIVE CATALYSIS .74. LIGAND EXCESS AND INTERMEDIATES IN THE RHODIUM-CATALYZED ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH PYRIDINEOXAZOLINE LIGANDS [J].
BRUNNER, H ;
BRANDL, P .
TETRAHEDRON-ASYMMETRY, 1991, 2 (09) :919-930
[5]  
BRUNNER H, 1992, Z NATURFORSCH B, V47, P609
[6]   ASYMMETRIC CATALYSIS .56. ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH A RHODIUM PICOLINEOXAZOLINE CATALYST 1-1 [J].
BRUNNER, H ;
BRANDL, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (03) :C81-C83
[7]  
BRUNNER H, 1991, Z NATURFORSCH B, V46, P1145
[8]  
BRUNNER H, 1993, CATALYTIC ASYMMETRIC, P303
[9]  
BRUNNER H, IN PRESS SYNTHESIS
[10]   ASYMMETRIC PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION USING PHOSPHORUS-CONTAINING OXAZOLINE LIGANDS [J].
DAWSON, GJ ;
FROST, CG ;
WILLIAMS, JMJ .
TETRAHEDRON LETTERS, 1993, 34 (19) :3149-3150
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