POLYMER-SUPPORTED CERIC(IV) CATALYST .1. CATALYTIC RING-OPENING OF EPOXIDES

被引：47

作者：

TAMAMI, B

IRANPOOR, N

ZARCHI, MAK

机构：

[1] Chemistry Department, Shiraz University, Shiraz

来源：

POLYMER | 1993年 / 34卷 / 09期

关键词：

POLYMER-SUPPORTED CERIC(IV) CATALYST; EPOXIDE RING OPENING;

D O I：

10.1016/0032-3861(93)90457-L

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(vinyl pyridine)-supported ceric(IV) complex can be easily prepared. It catalyses nucleophilic ring opening of epoxides in alcohols under mild conditions with high regio- and stereoselectivity. The reaction work-up is easy and the catalyst can be reused several times without its activity changing appreciably. Regeneration of the catalyst is easily achieved.

引用

页码：2011 / 2013

页数：3