MECHANISM OF OXIDATION OF CYCLOHEXANE BY THE RADICAL CATION OF PYRIDINE N-OXIDE

被引：2

作者：

KULAKOVSKAYA, SI ^{[1
]}

SHAMAEV, SN ^{[1
]}

BERDNIKOV, VM ^{[1
]}

机构：

[1] NN SEMENOV CHEM PHYS INST,CHERNOGOLOVKA,USSR

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 07期

关键词：

D O I：

10.1007/BF00957834

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of pyridine N-oxide in the presence of cyclohexane was studied on platinum and carbon glass rotating disk electrodes using the method of cyclic voltammetry in 0.2 N LiClO4 in acetonitrile. It was hypothesized that the electrochemically generated N-oxide radical cation reacts with cyclohexane according to the mechanism of hydrogen atom cleavage.

引用

页码：1345 / 1348

页数：4

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