CONDUCTOMETRIC AND HIGH-FREQUENCY DIELECTRIC-PROPERTIES OF THE POLY(PHENYLACETYLENE) IODINE SYSTEM IN TETRAHYDROFURAN SOLUTIONS

被引：7

作者：

CAMETTI, C ^{[1
]}

FURLANI, A ^{[1
]}

IUCCI, G ^{[1
]}

RUSSO, MV ^{[1
]}

机构：

[1] UNIV ROME LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

来源：

SYNTHETIC METALS | 1992年 / 51卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(92)90251-D

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrical properties of iodine-doped poly(phenylacetylene) [PPA] solutions have been studied by means of low-frequency electrical conductivity and dielectric measurements in the frequency range 1 MHz-1 GHz. These data show that, in these systems, the conducting mechanism is different and more complicated than the typical additive behaviour of diluted ionic solutions. The high-frequency dielectric measurements display a pronounced dielectric dispersion characterized by a single Debye-type relaxation process. This dielectric behaviour can be attributed to the dipolar character of PPA, enhanced when the polymer interacts with the iodine doping species.

引用

页码：45 / 54

页数：10

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