CHEMICALLY ACTIVATED METHYLCYCLOBUTANE FROM THE 337.1 NM PHOTOLYSIS OF KETENE IN THE PRESENCE OF CYCLOBUTANE - DEPENDENCE OF S-D ON EXTENT OF PHOTOLYSIS

被引：9

作者：

KOLLN, WS

JOHNSON, M

PEEBLES, DE

SIMONS, JW

机构：

[1] Department of Chemistry, New Mexico State University, Las Cruces

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)80132-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The 3371 A photolysis of ketene/cyclobutane/oxygen mixtures gave stabilization/decomposition ratios for chemically activated methylcyclobutane that varied with the extent of photolysis. Experiments designed to circumvent this complication gave a 10 ± 2 kcal/mole collisional deactivation step size for cyclobutane. © 1979.

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页码：85 / 88

页数：4

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