FERROMAGNETIC INTERMOLECULAR COUPLING IN THE NITRONYL NITROXIDE RADICAL 2-(4-THIOMETHYLPHENYL)-4,4,5,5-TETRAMETHLIMIDAZOLINE-1-OXYL-3-OXIDE, NIT(SME)PH

被引：33

作者：

CANESCHI, A ^{[1
]}

FERRARO, F ^{[1
]}

GATTESCHI, D ^{[1
]}

LELIRZIN, A ^{[1
]}

RENTSCHLER, E ^{[1
]}

机构：

[1] UNIV FLORENCE,DIPARTIMENTO CHIM,I-50144 FLORENCE,ITALY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 235卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; FERROMAGNETIC COUPLING; NITRONYL RADICAL; NITROXIDE RADICAL;

D O I：

10.1016/0020-1693(95)90057-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nitronyl nitroxide radical, 2-(4-thiomethylphenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide, hereafter denoted NIT(SMe)Ph, has been synthesized and the crystal structure solved. The space group and lattice parameters are P2(1)/a (Z=4), with a = 9.437(2), b = 19.827(2), c = 8.516(2)Angstrom and beta = 113.66(1)degrees. The magnetic behavior shown by this compound is dominated by ferromagnetic intermolecular coupling, as shown by magnetic measurements and single crystal EPR spectra.

引用

页码：159 / 164

页数：6

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