COMPLEXES WITH ASYMMETRIC TETRAAMINE LIGANDS .6. PHOTOAQUATION OF RHODIUM(III) COMPLEXES

被引：0
|
作者：
MUIR, MM
TORRES, LM
机构：
[1] Department of Chemistry, University of Puerto Rico, Rio Piedras
来源：
INORGANICA CHIMICA ACTA | 1992年 / 193卷 / 01期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0020-1693(00)83799-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ligand field photolyses of the dichloro complexes [Rh(Me(n)trien)Cl2]X (X = Cl- or ClO4-; n = 0, 2 or 3) were carried out and the quantum yields for Cl- release were determined. The stereochemistry of each of the chloroaquo photoproducts was characterized. The cis-alpha and trans isomers gave complete retention of configuration, but the cis-beta isomers rearranged to give the trans chloroaquo products. The methyl substituents on the ligands had no effect on the stereochemical course of the reactions but did affect the quantum yields.
引用
收藏
页码：87 / 92
页数：6
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