Aquabis(3-chlorobenzoato-kappa O)bis(N,N-diethylnicotinamide-kappa N)copper(II)

被引:3
|
作者
Bozkurt, Nihat [1 ]
Tunc, Tuncay [2 ]
Delibas, Nagihan Caylak [3 ]
Necefoglu, Hacali [1 ]
Hokelek, Tuncer [4 ]
机构
[1] Kafkas Univ, Dept Chem, TR-36100 Kars, Turkey
[2] Aksaray Univ, Sci Educ Dept, TR-68100 Aksaray, Turkey
[3] Sakarya Univ, Dept Phys, TR-54187 Sakarya, Turkey
[4] Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词
data-to-parameter ratio = 27.8; meanω(C - C) = 0.003 A °; Rfactor = 0.032; single-crystal X-ray study; T = 296 K; wRfactor = 0.086;
D O I
10.1107/S1600536813018989
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu(C7H4ClO2)(2)(C10K14N2O)2(H2O)], has twofold symmetry with the Cull cation and the O atom of the coordinating water molecule located on the axis. The Cull cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6). In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)degrees. In the crystal, O-H center dot center dot center dot O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction.
引用
收藏
页码:M458 / +
页数:9
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