The Kinetics and Mechanism for the Oxidation of Nicotinic Acid by Peroxomonosulfate in Acidic Aqueous Medium

被引：1

作者：

Agrawal, Anju ^{[1
]}

Sailani, Riya ^{[1
]}

Gupta, Beena ^{[1
]}

Khandelwal, C. L. ^{[1
]}

Sharma, P. D. ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302055, Rajasthan, India

来源：

JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE | 2012年 / 56卷 / 02期

关键词：

Kinetics; Mechanism; Oxidation; Nicotinic acid; Peroxomonosulfate;

D O I：

10.5012/jkcs.2012.56.2.212

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of nicotinic acid by peroxomonosulfate (PMS) has been studied in acetate buffers. Stoichiometry of the reaction corresponds to the reaction of one mole of the oxidant with a mole of nicotinic acid. N ->\O product has been confirmed both by UV visible and IR spectroscopy. The reaction is second order viz. first order with respect to each reactant. Activation parameters have also been evaluated. A plausible reaction mechanism is mentioned and the derived kinetic rate law accounts for experimental observations.

引用

页码：212 / 216

页数：5

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