Crystal structure of dimethyl 3,3 '-[(3-nitrophenyl)methylene]bis(1H-indole-2-carboxylate) ethanol monosolvate

被引:2
|
作者
Sun, Hong-Shun [1 ]
Li, Yu-Long [1 ]
Jiang, Hang [1 ]
Xu, Ning [1 ]
Xu, Hong [1 ]
机构
[1] Nanjing Coll Chem Technol, Dept Chem Engn, Nanjing 210048, Jiangsu, Peoples R China
关键词
indole; crystal structure; MRI contrast agent;
D O I
10.1107/S1600536814022296
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C27H21N3O6 center dot C2H5OH, the indole ring systems are approximately perpendicular to each other, with a dihedral angle of 89.3 (5)degrees; the plane of the benzene ring is oriented with respect to the indole ring systems at 49.9 (5) and 73.4 (3)degrees. In the crystal, molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds and weak C-H center dot center dot center dot pi interactions into a threedimensional supramolecular architecture. A void of 33.0 (7) angstrom(3) is observed in the crystal structure. The solvent ethanol molecule acts as a donor, forming an O-H center dot center dot center dot O hydrogen bond, reinforcing the framework structure.
引用
收藏
页码:370 / +
页数:10
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