PHOTOINDUCED ELECTRON-TRANSFER REACTION OF DIFLUORODIIODOMETHANE WITH AZA-AROMATIC COMPOUNDS AND ENAMINES

被引：35

作者：

CHEN, QY

LI, ZT

机构：

[1] Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 06期

关键词：

D O I：

10.1039/p19930000645

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Irradiation of difluorodiiodomethane 1 with pyrroles. indole and imidazoles in dimethylformamide gives the corresponding trifluoromethylated products, whereas irradiation with enamines results in 2-trifluoromethyl ketones. A photoinduced electron-transfer mechanism is proposed.

引用

页码：645 / 648

页数：4

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