PHOTOINDUCED ELECTRON-TRANSFER REACTION OF DIFLUORODIIODOMETHANE WITH AZA-AROMATIC COMPOUNDS AND ENAMINES

被引：35
|
作者：
CHEN, QY
LI, ZT
机构：
[1] Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 06期
关键词：
D O I：
10.1039/p19930000645
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Irradiation of difluorodiiodomethane 1 with pyrroles. indole and imidazoles in dimethylformamide gives the corresponding trifluoromethylated products, whereas irradiation with enamines results in 2-trifluoromethyl ketones. A photoinduced electron-transfer mechanism is proposed.
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页码：645 / 648
页数：4
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