SPECTRAL STUDIES ON COUMARINS AND DETERMINATION OF CONSTITUTION OF EKERSENIN BY TOTAL SYNTHESIS

被引：22

作者：

OKOGUN, JI

ENYENIHI, VU

EKONG, DEU

机构：

[1] Department of Chemistry, University of Ibadan, Ibadan

来源：

TETRAHEDRON | 1978年 / 34卷 / 08期

关键词：

D O I：

10.1016/0040-4020(78)80149-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

During the determination of the constitution of ekersenin isolated from Ekererbegia senegalensis, eight isomeric monomethoxy-monomethylcoumarins were synthesised. These studies proved that ekersenin was 4-methoxy-5-methylcoumarin, a constitution with novel biosynthetic implications. Apparently ekersenin is the first example of natural coumarin biosynthesis involving only the polyketide route. Comparative spectral correlations on substituted coumarins are summarised. © 1978.

引用

页码：1221 / 1224

页数：4

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