REACTIVITY OF ANIONIC ZIRCONAOXIRANES TOWARD METAL-CARBONYLS - IMPLICATIONS FOR THE MECHANISM OF HOMOGENEOUSLY CATALYZED CARBON-MONOXIDE HYDROGENATION

被引：10
作者：
ASKHAM, FR
CARROLL, KM
BRIGGS, PM
RHEINGOLD, AL
HAGGERTY, BS
机构：
[1] Department of Chemistry and Biochemistry, University of Delaware, Newark
来源：
ORGANOMETALLICS | 1994年 / 13卷 / 06期
关键词：
D O I：
10.1021/om00018a001
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of anionic zirconocene eta2-aldehyde complexes with metal carbonyls lead to rapid and quantitative formation of heterobimetallic complexes containing a new carbon-carbon bond, thereby suggesting a modified mechanism for homogeneously catalyzed carbon monoxide hydrogenation. Nine new bimetallic complexes are reported, including the X-ray structure of (eta5-C5H4Me)2Zr(Me){OCH(C6H4Me)C(O)Fe(CO)4]Li-(THF)2.
引用
收藏
页码：2139 / 2140
页数：2
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