HYDROSILYLATION CATALYZED BY ORGANONEODYMIUM COMPLEXES

被引：145
|
作者：
SAKAKURA, T [1 ]
LAUTENSCHLAGER, HJ [1 ]
TANAKA, M [1 ]
机构：
[1] NATL CHEM LAB IND,TSUKUBA,IBARAKI 305,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期
关键词：
D O I：
10.1039/c39910000040
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[(C5Me5)2NdH]2 and (C5Me5)2NdCH(SiMe3)2 effectively catalyse the hydrosilylation of alkenes with di- or tri-hydrosilanes at 30 to 80-degrees-C; the regioselectivity in the reaction of styrene depends to a considerable extent on the substituents of the silanes.
引用
收藏
页码：40 / 41
页数：2
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