CHEMICAL CONSTITUTION AND ACTIVITY OF BIPYRIDYLIUM HERBICIDES .4. DIQUATERNARY SALTS OF METHYL SUBSTITUTED 1,10-PHENANTHROLINES

被引:22
作者
DICKESON, JE
SUMMERS, LA
机构
[1] The University of Newcastle, New South Wales
关键词
D O I
10.1002/jsfa.2740200203
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Eight bridged diquaternary salts of methyl substituted 1,10‐phenanthrolines have been prepared. They are reduced in aqueous solution to radical cations at about the same potential as diquat by a one electron transfer which is largely reversed by air. in herbicidal tests they showed slight activity at a rate equivalent to 8 lb/acre. Their relatively poor phytotoxic properties are considered to be due to their large size which hinders their reaching the site of biological action of the bipyridylium herbicides. Copyright © 1969 John Wiley & Sons, Ltd
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页码:74 / &
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