RHODIUM(I) AND PLATINUM(II) COMPLEXES OF AMINOMETHYLPHOSPHINES AS HYDROGENATION AND HYDROFORMYLATION CATALYSTS

被引：11
|
作者：
HOYE, PAT
KEMMITT, RDW
LAW, DL
机构：
[1] UNIV LEICESTER,INORGAN RES LABS,LEICESTER LE1 7RH,ENGLAND
[2] ITC ALBRIGHT & WILSON LTD,W MIDLANDS B694 4LN,ENGLAND
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 1993年 / 7卷 / 07期
关键词：
HYDROGENATION; HYDROFORMYLATION; RHODIUM(I); PLATINUM(II); AMINOALKYLPHOSPHINES; CATALYST;
D O I：
10.1002/aoc.590070710
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Hydrogenation of alpha-acetamidocinnamic acid with chiral aminomethylphosphine complexes of rhodium(I), [Rh(cyclo-octa-1,5-diene) {(R2PCH2)2NR1}]-PF6 (R = Ph or Cy, R1 = D(+)-CHMePh, L-CHMeCO2Et, (R)(+)-bornyl) shows no asymmetric induction. The hydroformylation of styrene using the catalyst mixture [PtCl2(P - P)]/SnCl2, Shows asymmetric induction with up to 31% enantiomeric excess of 2-phenyl-propanol being observed.
引用
收藏
页码：513 / 516
页数：4
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