HOMOLYTIC AND HETEROLYTIC CLEAVAGE ENERGIES FOR CARBON NITROGEN BONDS

被引：26

作者：

ARNETT, EM

VENIMADHAVAN, S

AMARNATH, K

机构：

[1] Department of Chemistry, Duke University, Durham

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 14期

关键词：

D O I：

10.1021/ja00040a018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using calorimetric and electrochemical techniques described in previous reports, we have determined the heterolytic and homolytic bond energies at 25-degrees-C in sulfolane for the carbon-nitrogen bonds in the compounds produced by reactions of nine resonance-stabilized carbenium ions with nitranions formed by deprotonating the following nitrogen acids: succinimide, phthalimide, carbazole, and 3,6-dibromocarbazole.

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页码：5598 / 5602

页数：5

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