RU(BIPY)2DPPZ2+ - A HIGHLY SENSITIVE LUMINESCENT PROBE FOR MICELLAR SODIUM DODECYL-SULFATE SOLUTIONS

被引：88

作者：

CHAMBRON, JC

SAUVAGE, JP

机构：

[1] Laboratoire de Chimie Organo-Minérale, Université Louis Pasteur, Institut de Chimie, 67000 Strasbourg, 1, rue Blaise Pascal

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 182卷 / 06期

关键词：

D O I：

10.1016/0009-2614(91)90132-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The luminescence of Ru(bipy)2dppz2+ (dppz is dipyrido[3,2-a:2',3'-c]phenazine) was previously shown to be totally quenched in water solutions, whereas the complex is luminescent in organic solvents. In sodium dodecyl sulfate aqueous solutions, this complex luminesces strongly above the critical micellar concentration. This latter result correlates well with the observations in alcoholic solvents with long alkyl chains. It is interpreted in terms of the shielding of the dipyridophenazine ligand (at which quenching of the emission occurs) from the water molecules by the micellar core.

引用

页码：603 / 607

页数：5

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