AN ESR STUDY OF SHORT-LIVED RADICALS DERIVED FROM PYRIMIDINES IN AQUEOUS SOLUTION

被引：60
作者：
NICOLAU, C
MCMILLAN, M
NORMAN, ROC
机构：
[1] Department of Chemistry, The University of York Heslington, York, England
来源：
BIOCHIMICA ET BIOPHYSICA ACTA | 1969年 / 174卷 / 02期
关键词：
D O I：
10.1016/0005-2787(69)90272-X
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
1. 1. The electron spin resonance spectra of the short-lived radicals which are formed by the reaction, in aqueous solution, between various pyrimidines and the hydroxyl or amino radical have been determined. 2. 2. The hyperfine splitting constants and the g-factors of these and related radicals have been used to assign the spectra to specific structures. 3. 3. The similarities and differences between these results and those obtained when the formation of radicals from the pyrimidines is induced in the solid state are noted. © 1969.
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页码：413 / &
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