THE INFLUENCE OF MICROWAVE-HEATING ON THE MORPHOLOGY AND BENZENE HYDROGENATION ACTIVITY OF ALUMINA-SUPPORTED AND SILICA-SUPPORTED PALLADIUM CATALYSTS

被引:20
|
作者
PRASAD, PSS [1 ]
LINGAIAH, N [1 ]
RAO, PK [1 ]
BERRY, FJ [1 ]
SMART, LE [1 ]
机构
[1] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND
关键词
ALUMINA-SUPPORTED PALLADIUM CATALYST; SILICA-SUPPORTED PALLADIUM CATALYST; MICROWAVE HEATING; X-RAY POWDER DIFFRACTION; TEMPERATURE-PROGRAMMED REDUCTION; BENZENE HYDROGENATION; NITROGEN ADSORPTION; HYDROGEN CHEMISORPTION;
D O I
10.1007/BF00807191
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alumina- and silica-supported palladium catalysts were prepared by conventional and microwave heating. The catalysts have been characterized by nitrogen adsorption, hydrogen chemisorption, X-ray powder diffraction and temperature-programmed reduction and tested for benzene hydrogenation activity. The results show that preparation of samples by microwave heating leads to enhanced crystallite size and increased hydrogenation activity.
引用
收藏
页码:345 / 351
页数:7
相关论文
共 11 条
  • [1] Microwave heating during catalyst preparation: influence on the hydrodechlorination activity of alumina-supported palladium-iron bimetallic catalysts
    Berry, FJ
    Smart, LE
    Prasad, PSS
    Lingaiah, N
    Rao, PK
    APPLIED CATALYSIS A-GENERAL, 2000, 204 (02) : 191 - 201
  • [2] Hydrogenation of benzene over alumina-supported nickel catalysts prepared from Ni(II) acetylacetonate
    Molina, R
    Poncelet, G
    JOURNAL OF CATALYSIS, 2001, 199 (02) : 162 - 170
  • [3] Characterisation of alumina- and silica-supported vanadium sulphide catalysts and their performance in hydrotreating reactions
    Janssens, JP
    van Langeveld, AD
    Moulijn, JA
    APPLIED CATALYSIS A-GENERAL, 1999, 179 (1-2) : 229 - 239
  • [4] Size-Dependent Sulfur Poisoning of Silica-Supported Monodisperse Pt Nanoparticle Hydrogenation Catalysts
    Baldyga, Lyndsey M.
    Blavo, Selasi O.
    Kuo, Chun-Hong
    Tsung, Chia-Kuang
    Kuhn, John N.
    ACS CATALYSIS, 2012, 2 (12): : 2626 - 2629
  • [5] Effect of Iron Content in Alumina-Supported Palladium Catalysts and Their Reduction Conditions on Diclofenac Hydrodechlorination in an Aqueous Medium
    Lokteva, E. S.
    Pesotskiy, M. D.
    Golubina, E. V.
    Maslakov, K. I.
    Kharlanov, A. N.
    Shishova, V. V.
    Kaplin, I. Yu.
    Maksimov, S. V.
    KINETICS AND CATALYSIS, 2024, 65 (02) : 133 - 154
  • [6] A Comparison of Experimental Procedures for the Application of Infrared Spectroscopy to Probe the Surface Morphology of an Alumina-Supported Palladium Catalyst
    McCullagh, A. M.
    Warringham, R.
    Morisse, C. G. A.
    Gilpin, L. F.
    Brennan, C.
    Mitchell, C. J.
    Lennon, D.
    TOPICS IN CATALYSIS, 2021, 64 (17-20) : 1010 - 1020
  • [7] A Comparison of Experimental Procedures for the Application of Infrared Spectroscopy to Probe the Surface Morphology of an Alumina-Supported Palladium Catalyst
    A. M. McCullagh
    R. Warringham
    C. G. A. Morisse
    L. F. Gilpin
    C. Brennan
    C. J. Mitchell
    D. Lennon
    Topics in Catalysis, 2021, 64 : 1010 - 1020
  • [8] Role of potassium on the structure and activity of alumina-supported vanadium oxide catalysts for propane oxidative dehydrogenation
    Cortez, GG
    Fierro, JLG
    Bañares, MA
    CATALYSIS TODAY, 2003, 78 (1-4) : 219 - 228
  • [9] The influence of MoS2 slab 2D morphology and edge state on the properties of alumina-supported molybdenum sulfide catalysts
    Baubet, Bertrand
    Devers, Elodie
    Hugon, Antoine
    Leclerc, Emmanuel
    Afanasiev, Pavel
    APPLIED CATALYSIS A-GENERAL, 2014, 487 : 72 - 81
  • [10] The nature of the sulfur tolerance of amorphous silica-alumina supported NiMo(W) sulfide and Pt hydrogenation catalysts
    Coumans, Alessandro E.
    Poduval, Dilip G.
    van Veen, J. A. Rob
    Hensen, Emiel J. M.
    APPLIED CATALYSIS A-GENERAL, 2012, 411 : 51 - 59