ACOUSTICAL DETERMINATION OF A SOLUTE PARTITION-COEFFICIENT BETWEEN 2 IMMISCIBLE SOLVENTS

被引：8
作者：
BABINCOVA, M
HIANIK, T
机构：
[1] Department of Biophysics, Comenius University, 84215 Bratislava, MFF UK, Mlynská dolina
来源：
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1994年 / 185卷
关键词：
PARTITION COEFFICIENT; ULTRASONIC VELOCIMETRY; LIPID; ETHANOL;
D O I：
10.1524/zpch.1994.185.Part_1.145
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new method, based on the precision measurement of ultrasonic velocity in a system consisting of the studied solute and two immiscible solvents, is developed for the determination of the partition coefficient. The method has been used for the determination of the ethanol partition coefficient between lipid and water solvents.
引用
收藏
页码：145 / 148
页数：4
相关论文
共 8 条
[1]  
BABINCOVA M, 1992, ACTA PHYS U COMEN, V33, P103
[2]   MEASUREMENT OF ANOMALOUSLY HIGH HYDRATION OF (DA)N.(DT)N DOUBLE HELICES IN DILUTE-SOLUTION [J].
BUCKIN, VA ;
KANKIYA, BI ;
BULICHOV, NV ;
LEBEDEV, AV ;
GUKOVSKY, IY ;
CHUPRINA, VP ;
SARVAZYAN, AP ;
WILLIAMS, AR .
NATURE, 1989, 340 (6231) :321-322
[3]   ULTRASONIC STUDY OF PROTON-TRANSFER REACTIONS IN AQUEOUS-SOLUTIONS OF AMINO-ACIDS [J].
CHALIKIAN, TV ;
KHARAKOZ, DP ;
SARVAZYAN, AP ;
CAIN, CA ;
MCGOUGH, RJ ;
POGOSOVA, IV ;
GAREGINIAN, TN .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (02) :876-883
[4]   ALCOHOLS DEHYDRATE LIPID-MEMBRANES - AN INFRARED STUDY ON HYDROGEN-BONDING [J].
CHIOU, JS ;
KRISHNA, PR ;
KAMAYA, H ;
UEDA, I .
BIOCHIMICA ET BIOPHYSICA ACTA, 1992, 1110 (02) :225-233
[5]  
DIAMOND JM, 1974, J MEMBRANE BIOL, V17, P101
[6]   VOLUMETRIC PROPERTIES OF PROTEINS AND THEIR ANALOGS IN DILUTED WATER SOLUTIONS .1. PARTIAL VOLUMES OF AMINO-ACIDS AT 15-55-DEGREES-C [J].
KHARAKOZ, DP .
BIOPHYSICAL CHEMISTRY, 1989, 34 (02) :115-125
[7]   PARTITION COEFFICIENTS AND THEIR USES [J].
LEO, A ;
HANSCH, C ;
ELKINS, D .
CHEMICAL REVIEWS, 1971, 71 (06) :525-+
[8]   ULTRASONIC VELOCIMETRY OF BIOLOGICAL COMPOUNDS [J].
SARVAZYAN, AP .
ANNUAL REVIEW OF BIOPHYSICS AND BIOPHYSICAL CHEMISTRY, 1991, 20 :321-342
1