GENERATION AND REACTION OF SAMARIUM(II) IODIDE EQUIVALENT FROM SAMARIUM AND CHLOROTRIMETHYLSILANE SODIUM-IODIDE SYSTEM IN ACETONITRILE

被引：35

作者：

AKANE, N ^{[1
]}

KANAGAWA, Y ^{[1
]}

NISHIYAMA, Y ^{[1
]}

ISHII, Y ^{[1
]}

机构：

[1] KANSAI UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 564, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 12期

关键词：

D O I：

10.1246/cl.1992.2431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Samarium(II) iodide equivalent was generated from metallic samarium and Me3SiCl/Nal reagent in acetonitrile under ambient conditions. Dehalogenation of alpha-halocarbonyl compounds and reductive coupling of ketones were successfully carried out by the use of the samarium(II) species, thus generated, in acetonitrile.

引用

页码：2431 / 2434

页数：4

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