GENERATION AND REACTION OF SAMARIUM(II) IODIDE EQUIVALENT FROM SAMARIUM AND CHLOROTRIMETHYLSILANE SODIUM-IODIDE SYSTEM IN ACETONITRILE

被引：35
|
作者：
AKANE, N [1 ]
KANAGAWA, Y [1 ]
NISHIYAMA, Y [1 ]
ISHII, Y [1 ]
机构：
[1] KANSAI UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 564, JAPAN
来源：
CHEMISTRY LETTERS | 1992年 / 12期
关键词：
D O I：
10.1246/cl.1992.2431
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Samarium(II) iodide equivalent was generated from metallic samarium and Me3SiCl/Nal reagent in acetonitrile under ambient conditions. Dehalogenation of alpha-halocarbonyl compounds and reductive coupling of ketones were successfully carried out by the use of the samarium(II) species, thus generated, in acetonitrile.
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页码：2431 / 2434
页数：4
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