STRUCTURES OF COLCHICINE ANALOGS .5. 2-METHOXY-5-(4-METHOXYPHENYL)CYCLOHEPTA-2,4,6-TRIEN-1-ONE

被引：4

作者：

GULBIS, JM ^{[1
]}

MACKAY, MF ^{[1
]}

BANWELL, MG ^{[1
]}

LAMBERT, JN ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270191009411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C15H14O3, M(r) = 242.3, monoclinic, Pc, a = 13.219 (1), b = 7.072 (1), c = 6.527 (2) angstrom, beta = 97.23 (1)-degrees, V = 605.3 (3) angstrom 3, Z = 2, D(m) (flotation) = 1.33 (1), D(x) = 1.329 Mg m-3, lambda(Cu K-alpha) = 1.5418 angstrom, mu(Cu K-alpha) = 0.66 mm-1, F(000) = 256, T = 291 (1) K, final R = 0.040 for 905 observed data. The bicyclic molecule adopts a conformation similar to the solid-state conformation of isocolchicine, and the dihedral angle between the planes of the two rings is 41.1 (4)-degrees.

引用

页码：332 / 334

页数：3

共 50 条

[1] STRUCTURES OF COLCHICINE ANALOGS .3. 2-METHOXY-5-(2',3'-DIMETHOXYPHENYL)CYCLOHEPTA-2,4,6-TRIEN-1-ONE AND 2-METHOXY-5-(3',4'-DIMETHOXYPHENYL)CYCLOHEPTA-2,4,6-TRIEN-1-ONE
GABLE, RW
MACKAY, MF
BANWELL, MG
LAMBERT, JN
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1308 - 1312
[2] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, AND ANTIMITOTIC PROPERTIES OF 6-CHLORO-2-METHOXY-5-(2',3',4'-TRIMETHOXYPHENYL)CYCLOHEPTA-2,4,6-TRIEN-1-ONE, A BICYCLIC ANALOG OF COLCHICINE
BANWELL, MG
HERBERT, KA
BUCKLETON, JR
CLARK, GR
RICKARD, CEF
LIN, CM
HAMEL, E
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (21): : 4945 - 4952
[3] THERMAL DEDIAZONIATION OF AN ARYLDIAZONIUM SALT IN CYCLOHEPTA-2,4,6-TRIEN-1-ONE - ISOLATION AND CHARACTERIZATION OF A NOVEL ARYLOXYTROPYLIUM SALT
HANCOCK, RA
HILL, H
JOURNAL OF CHEMICAL RESEARCH-S, 1984, (02): : 68 - 69
[4] 2-(3,5-Dinitropyridyl-2-oxy)-3,5,7-trimethyl-cyclohepta-2,4,6-trien-1-one
Borbulevych, OY
Kurbatov, SV
Vaslyaeva, GS
Antipin, MY
Olekhnovich, LP
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1920 - 1921
[5] REACTIVITY OF PSEUDOAROMATIC COMPOUNDS .6. NUCLEOPHILIC SUBSTITUTION WITH REARRANGEMENT ON TROPONOIDS - REACTION OF 2-(1-AZONIABICYCLO[2.2.2]OCT-1-YL[3,5,7-H-2(3)]-CYCLOHEPTA-2,4,6-TRIEN-1-ONE IODIDE WITH PIPERIDINE LEADING TO 2-PIPERIDINO[4,6 "H-2(2)]CYCLOHEPTA-2,4,6-TRIEN-1-ONE VIA 7,2 ADDITION-ELIMINATION
BIGGI, G
DELCIMA, F
PIETRA, F
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (13) : 4700 - &
[6] 2-amino-5-[4-(octylamino)phenyl]cyclo-hepta-2,4,6-trien-1-one
Kubo, K
Matsumoto, T
Katahira, K
Mori, A
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O2750 - O2752
[7] 2-hydroxy-7-iodocyclohepta-2,4,6-trien-1-one
Kubo, Kanji
Matsumoto, Taisuke
Mori, Akira
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : o1297 - o1299
[8] 2-Hydroxy-7-nitrocyclohepta-2,4,6-trien-1-one
Lyczko, Krzysztof
Lyczko, Monika
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O536 - +
[9] Bis[μ-2-(1,4,7,10-tetraoxa-13-aza-cyclopentadeca-13-yl)cyclohepta-2,4,6-trien-1-one]bis[bis(thiocyanato)- barium(II)]
Yamamoto, E
Kubo, K
Kato, N
Mori, A
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : E329 - E330
[10] Reaction of 1,2,3,4,5,6,7-(heptamethoxycarbonyl)cyclohepta-2,4,6-trien-1-yl potassium with tropylium tetrafluoroborate to form cage structures
Tomilov, Yury V.
Platonov, Dmitry N.
Shulishov, Evgeny V.
Okonnishnikova, Galina P.
TETRAHEDRON, 2013, 69 (33) : 6855 - 6860

← 1 2 3 4 5 →