Electrochemical Renewal Method for Enhancing Cyclic Ability of Lead-Acid Battery

被引:1
作者
Tae, Uk [1 ]
Yang, Jeong-jin [1 ]
Hong, Kyoung-mi [2 ]
Kim, Han-joo [2 ]
Park, Soo-gil [1 ]
机构
[1] Chungbuk Natl Univ, Dept Ind Engn Chem, Cheongju 361763, South Korea
[2] PureEchem Co ltd, Jicji Daero Beon Gil 60, Cheongju 361290, South Korea
来源
JOURNAL OF THE KOREAN ELECTROCHEMICAL SOCIETY | 2012年 / 15卷 / 03期
关键词
Lead-acid battery; Lead sulfate;
D O I
10.5229/JKES.2012.15.3.160
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The lead-acid batteries are the most often used in human life, because of their low cost, good reversibility and high potential but they have limit cycle ability with low capacitance. The main causes of this problem are forming recrystallization of PbSO4 on electrodes surface during cycles which the recrystallization of PbSO4 is known as sulfation. In this study, formation process of sulfation was investigated depending on charge and discharge cycle numbers. And we decomposed sulfation to renew cycle ability of lead-acid batteries. The renewed lead-acid batteries recovered to 84% compared to first capacity after 600 cycles.
引用
收藏
页码:160 / 164
页数:5
相关论文
共 7 条
[1]   Sulfation in lead-acid batteries [J].
Catherino, HA ;
Feres, FF ;
Trinidad, F .
JOURNAL OF POWER SOURCES, 2004, 129 (01) :113-120
[2]  
Kim Y., 2012, Korea Patent, Patent No. 1020120029014
[3]  
Linden D, 2001, HDB BATTERIES
[4]   A new process of lead recovery from waste lead-acid batteries by electrolysis of alkaline lead oxide solution [J].
Pan, Junqing ;
Zhang, Chao ;
Sun, Yanzhi ;
Wang, Zihao ;
Yang, Yusheng .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 19 :70-72
[5]  
Pompon J. P., 1989, INTELEC 9 C P PISC N
[6]   The lead/acid battery - A key technology for global energy management [J].
Rand, DAJ .
JOURNAL OF POWER SOURCES, 1997, 64 (1-2) :157-174
[7]   Aging mechanisms and service life of lead-acid batteries [J].
Ruetschi, P .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :33-44