SEPARATION OF GAS MIXTURES IN CHEMICAL EQUILIBRIUM IN A TEMPERATURE GRADIENT .2.

被引：3

作者：

PAUL, R

DEVRIES, AE

机构：

[1] F.O.M. Institute for Atomic and Molecular Physics, Amsterdam

[2] Department of General Physics and X-Rays, Indian Association for the Cultivation of Science

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 11期

关键词：

D O I：

10.1063/1.1668095

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The theory of separation of gas mixtures in chemical equilibrium has been verified experimentally for the systems: (a) Ar/He/NO2/N 2O4 and (b) 2NO2⇆NO+O2 with a large excess of O2. The separation in the second system was smaller than calculated, which was attributed to the slowness of the chemical reaction. This was tested by experiments with two different concentrations of NO 2. The results agree well with a simple model.

引用

页码：4867 / &