NOVEL DIMERIC STRUCTURE IN THE PD(II) COMPLEX OF 1,10-DITHIA[2](2,6)PYRIDINO[2](1,1')FERROCENOPHANE - A CONNECTED METAL-METAL INTERACTION

被引：14
|
作者：
SATO, M [1 ]
ASANO, H [1 ]
AKABORI, S [1 ]
机构：
[1] TOHO UNIV,FAC SCI,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)83179-Y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Pd(BF4)2 complex of 1,10-dithia[2](2,6)pyridino[2](1,1')ferrocenophane was prepared. The NMR spectral data suggested that the complex has a weak dative bond between the Pd and Fe atoms. The X-ray analysis of the complex supported the suggestion and also showed that a weak Pd-Pd bonding interaction connects two molecules, resulting in a novel dimeric structure.
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收藏
页码：105 / 109
页数：5
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