Ion Pair Association in Isodielectric Mixtures at 25 degrees C

被引：5

作者：

D'Aprano, Alessandro ^{[1
]}

Donato, Ines Dorina ^{[1
]}

Caponetti, Eugenio ^{[1
]}

机构：

[1] Univ Palermo, Inst Phys Chem, I-90123 Palermo, Italy

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1974年 / 3卷 / 05期

关键词：

Conductance; ion pair association; potassium perchlorate and iodide; aqueous mixtures; isodielectric solvents;

D O I：

10.1007/BF00646477

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Conductance measurements of potassium perchlorate and iodide have been carried out on the following mixtures: methanol-ethylene carbonate, acetone-ethylene carbonate, aeetonitrile-ethylene carbonate, sulfolane-ethylene carbonate, isodielectric with water; and in benzene-sulfolane, benzene-acetonitrile, ethanol-sulfolane, isodielectric with methanol. The extent of ionic association at a given concentration in two solvents of the same dielectric constant is greater in the aprotic solvent.

引用

页码：371 / 376

页数：6

共 50 条

[21] ION-PAIR FORMATION OF RUBIDIUM IODIDE IN 1-BUTANOL AT 25-DEGREES-C
BERONIUS, P
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1978, 32 (05): : 467 - 468
[22] THE EFFECT OF PRESSURE ON THE DISSOCIATION-CONSTANT OF HYDROFLUORIC-ACID AND THE ASSOCIATION CONSTANT OF THE NAF ION-PAIR AT 25-DEGREES-C
USHA, AV
ATKINSON, G
JOURNAL OF SOLUTION CHEMISTRY, 1992, 21 (05) : 477 - 488
[23] STUDIES IN ISODIELECTRIC MEDIA .4. THERMODYNAMICS OF PROTONATION OF PARA-NITROANILINE IN ETHYLENE-GLYCOL DIETHYLENE GLYCOL MIXTURES AT 25-DEGREES-C
PRASAD, PS
KALIDAS, C
MONATSHEFTE FUR CHEMIE, 1981, 112 (12): : 1369 - 1374
[24] THERMODYNAMIC PROPERTIES OF ACETONE AND CYCLOHEXANOL MIXTURES AT 25 DEGREES C
BENSON, GC
MURAKAMI, S
JONES, DEG
JOURNAL OF CHEMICAL THERMODYNAMICS, 1971, 3 (05): : 719 - &
[25] VOLUMES OF MIXTURES OF ALCOHOLS IN WATER AT 25-DEGREES-C
HETU, D
PERRON, G
JOURNAL OF SOLUTION CHEMISTRY, 1991, 20 (02) : 207 - 220
[26] ION ASSOCIATION OF (1-1) ELECTROLYTES IN PURE ALCOHOLS AT 25-DEGREES-C
HAFEZ, AM
SADEK, H
RAMADAN, MS
ELECTROCHIMICA ACTA, 1979, 24 (09) : 957 - 967
[27] THE ASSOCIATION OF IONS IN DIOXANE-WATER MIXTURES AT 25-DEGREES
MARTEL, RW
KRAUS, CA
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1955, 41 (01) : 9 - 20
[28] IDENTIFICATION OF ION-PAIR IN BETA-DICALCIUM-SILICATE-WATER SYSTEM AT 25-DEGREES-C
HELMY, FM
SHEBL, FA
SUMMAN, AM
CHEMIKER-ZEITUNG, 1988, 112 (06): : 207 - 209
[29] VOLUME AND COMPRESSIBILITY CHANGE FOR FORMATION OF LASO4+ ION-PAIR AT 25-DEGREES-C
CHEN, CT
MILLERO, FJ
JOURNAL OF SOLUTION CHEMISTRY, 1977, 6 (09) : 589 - 607
[30] DISSOCIATION CONSTANT OF BISELENATE ION AT 25 DEGREES C
COVINGTON, AK
DOBSON, JV
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (06): : 1435 - +

← 1 2 3 4 5 →