Ion Pair Association in Isodielectric Mixtures at 25 degrees C

被引：5
|
作者：
D'Aprano, Alessandro [1 ]
Donato, Ines Dorina [1 ]
Caponetti, Eugenio [1 ]
机构：
[1] Univ Palermo, Inst Phys Chem, I-90123 Palermo, Italy
来源：
JOURNAL OF SOLUTION CHEMISTRY | 1974年 / 3卷 / 05期
关键词：
Conductance; ion pair association; potassium perchlorate and iodide; aqueous mixtures; isodielectric solvents;
D O I：
10.1007/BF00646477
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Conductance measurements of potassium perchlorate and iodide have been carried out on the following mixtures: methanol-ethylene carbonate, acetone-ethylene carbonate, aeetonitrile-ethylene carbonate, sulfolane-ethylene carbonate, isodielectric with water; and in benzene-sulfolane, benzene-acetonitrile, ethanol-sulfolane, isodielectric with methanol. The extent of ionic association at a given concentration in two solvents of the same dielectric constant is greater in the aprotic solvent.
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页码：371 / 376
页数：6
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