THE EFFECT OF IONIC ADSORPTION ON ELECTROCHEMICAL REACTION-KINETICS

被引：0
|
作者：
KIRYANOV, VA
KRYLOV, VS
机构：
来源：
SOVIET ELECTROCHEMISTRY | 1979年 / 15卷 / 11期
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D O I：
暂无
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In terms of statistical mechanics, the local probability of the elementary act of irreversible electrochemical one-electron reactions is averaged while allowing for the electric double layer set up by the indifferent electrolyte and by ions specifically adsorbed at the metal/solution interface. An expression for the current density as a function of double-layer parameters is obtained and analyzed for the case where the discharging ions are situated outside the Helmholtz layer.
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页码：1387 / 1390
页数：4
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