COMPATIBILIZATION OF POLY(METHYL ACRYLATE) WITH POLY(METHYL METHACRYLATE) THROUGH CHARGE-TRANSFER INTERACTIONS

被引：4

作者：

RUSSELL, E ^{[1
]}

CRONE, G ^{[1
]}

NATANSOHN, A ^{[1
]}

机构：

[1] QUEENS UNIV,DEPT CHEM,KINGSTON K7L 3N6,ONTARIO,CANADA

来源：

POLYMER BULLETIN | 1991年 / 27卷 / 01期

关键词：

D O I：

10.1007/BF00296327

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymers of methyl acrylate (MA) with an electron-donor comonomer (N-vinylcarbazole) (NVC) are mixed with copolymers of methyl methacrylate (MMA) with a electron-acceptor comonomer (2-(3,5-dinitrobenzoyl)oxyethyl methacrylate) (DNBM) such that 1:1 mol ratios of NVC:DNBM are present at all times. The blends obtained are phase separated up to an average of 27 mol% donor/acceptor structural unit in the copolymer. Above 27 mol% "perturbation", poly(MA) and poly(MMA) become compatible.

引用

页码：67 / 72

页数：6

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