COMPATIBILIZATION OF POLY(METHYL ACRYLATE) WITH POLY(METHYL METHACRYLATE) THROUGH CHARGE-TRANSFER INTERACTIONS

被引：4
|
作者：
RUSSELL, E [1 ]
CRONE, G [1 ]
NATANSOHN, A [1 ]
机构：
[1] QUEENS UNIV,DEPT CHEM,KINGSTON K7L 3N6,ONTARIO,CANADA
来源：
POLYMER BULLETIN | 1991年 / 27卷 / 01期
关键词：
D O I：
10.1007/BF00296327
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Copolymers of methyl acrylate (MA) with an electron-donor comonomer (N-vinylcarbazole) (NVC) are mixed with copolymers of methyl methacrylate (MMA) with a electron-acceptor comonomer (2-(3,5-dinitrobenzoyl)oxyethyl methacrylate) (DNBM) such that 1:1 mol ratios of NVC:DNBM are present at all times. The blends obtained are phase separated up to an average of 27 mol% donor/acceptor structural unit in the copolymer. Above 27 mol% "perturbation", poly(MA) and poly(MMA) become compatible.
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页码：67 / 72
页数：6
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