On the model for a tunnelling methyl group

被引：2
|
作者：
Allen, P. S. [1 ]
Howard, C. J. [1 ]
机构：
[1] Univ Nottingham, Dept Phys, Nottingham NG7 2RD, England
来源：
CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 03期
关键词：
D O I：
10.1016/0009-2614(70)80208-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A model for the torsional ground state of a methyl rotor is presented in terms of single particle wave functions. Consequent on satisfying Pauli's exclusion principle, terms arise in the energy matrix elements which were absent from previous treatments.
引用
收藏
页码：169 / 171
页数：3
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