STATISTICAL THERMODYNAMICS OF MIXTURES OF RODLIKE PARTICLES .6. RODS CONNECTED BY FLEXIBLE JOINTS

被引：201

作者：

FLORY, PJ

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

MACROMOLECULES | 1978年 / 11卷 / 06期

关键词：

D O I：

10.1021/ma60066a016

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Solutions are treated in which the solute molecule comprises m rodlike sequences, each of axis ratio x, connected in linear succession by m-1 joints permitting free orientations. Separation of an anisotropic phase depends predominantly on x. Increasing the chain length from x to xm=mx by joining m rods affects the compositions of the phases coexisting at equilibrium by only a few percent. The implications of these. results on the behavior to be expected in systems of semirigid real chains of various types are discussed. © 1978, American Chemical Society. All rights reserved.

引用

页码：1141 / 1144

页数：4

共 12 条

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