COMPLEX RADICAL-ION SALTS OF TCNQ (TETRACYANOQUINODIMETHAN) WITH CYANINE DYE AND RELATED CATIONS

被引：56

作者：

KLANDERMAN, BH

HOESTEREY, DC

机构：

[1] Research Laboratories, Eastman Kodak Company, Rochester

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 01期

关键词：

D O I：

10.1063/1.1671734

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrical conductivities of the complex radical-ion salts of TCNQ (tetracyanoquinodimethan) with cyanine dye and related cations generally increase with an increase in the polarizability of the cation. With large cations, however, the increase expected from the high polarizability is offset by the size of the cation. From the change in conductivity of the complex TCNQ salts accompanying the variation in structure of the corresponding cations, a plausible structure for the complex salts can be postulated.

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页码：377 / +

页数：1

相关论文

共 13 条

[1] STRUCTURAL DATA ON ELECTRICALLY CONDUCTIVE CAESIUM TETRACYANOQUINODIMETHANIDE CS2()NC)2CC6H4C)CN)2)3 [J].

ARTHUR, P .

ACTA CRYSTALLOGRAPHICA, 1964, 17 (09) :1176-&

[2] SPIN CORRELATION IN ION RADICAL SALTS - SYSTEM (CS+)2(TCNQ)3= [J].

CHESNUT, DB ;

ARTHUR, P .

JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (11) :2969-+

[3]

DUPUIS P, 1967, CR ACAD SCI C CHIM, V265, P688

[4] CRYSTAL STRUCTURE OF 2-1 COMPLEX OF 7,7,8,8-TETRACYANOQUINODIMETHAN AND N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE (TCNQ)2- TMPD+ [J].

HANSON, AW .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :768-&

[5] ELECTRON CORRELATIONS IN NARROW ENERGY BANDS .4. ATOMIC REPRESENTATION [J].

HUBBARD, J .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1965, 285 (1403) :542-&

[6]

KAUZMANN W, 1957, QUANTUM CHEMISTRY, pCH16

[7] ELECTRONIC CONDUCTION AND EXCHANGE INTERACTION IN A NEW CLASS OF CONDUCTIVE ORGANIC SOLIDS [J].

KEPLER, RG ;

BIERSTEDT, PE ;

MERRIFIELD, RE .

PHYSICAL REVIEW LETTERS, 1960, 5 (11) :503-504

[8] ON ELECTRICAL CONDUCTIVITIES OF TETRACYANOQUINODIMETHAN ANION-RADICAL SALTS [J].

LEBLANC, OH .

JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (12) :4307-&

[9] TETRACYANOQUINODIMETHAN DERIVATIVES OF CYANINE DYES [J].

LUPINSKI, JH ;

WALTER, KR ;

VOGT, LH .

MOLECULAR CRYSTALS, 1967, 3 (02) :241-+

[10] SUBSTITUTED QUINODIMETHANS .2. ANION-RADICAL DERIVATIVES AND COMPLEXES OF 7,7,8,8-TETRACYANOQUINODIMETHAN [J].

MELBY, LR ;

MAHLER, W ;

MOCHEL, WE ;

HARDER, RJ ;

HERTLER, WR ;

BENSON, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (17) :3374-&