STUDIES ON STABILITY OF DITHIOCARBAMIC ACIDS

被引：61

作者：

ASPILA, KI

SASTRI, VS

CHAKRABARTI, CL

机构：

[1] Chemistry Department Carleton University Ottawa 1, Ont.

来源：

TALANTA | 1969年 / 16卷 / 07期

关键词：

D O I：

10.1016/0039-9140(69)80149-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The influence of the substituent on the nitrogen atom with respect to the rate and pattern of decomposition of N,N-disubstituted dithiocarbamie acids has been studied. The rates of decomposition with respect to such variables as pH, temperature (activation parameters) and heavy water medium (solvent isotope effect), have been determined, and a mechanism to accommodate the observed results has been proposed. © 1969.

引用

页码：1099 / +

页数：1

共 12 条

[1]

BELL RP, 1959, PROTON CHEMISTRY, P189

[2]

BODE H, 1954, Z ANAL CHEM, V142, P414

[3] USE OF GLASS ELECTRODE IN DEUTERIUM OXIDE AND RELATION BETWEEN STANDARDIZED PD (PAD) SCALE AND OPERATIONAL PH IN HEAVY WATER [J].