A new indirect application of aggregative activation: Synthesis of esters by cobalt-catalyzed carbonylation of aryl, heterocyclic, and vinyl halides under atmospheric pressure

被引：23

作者：

Marchal, J ^{[1
]}

Bodiguel, J ^{[1
]}

Fort, Y ^{[1
]}

Caubere, P ^{[1
]}

机构：

[1] UNIV NANCY 1,FAC SCI,INCM FU CNRS 0008,URA CNRS 457,LAB CHIM ORGAN 1,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 26期

关键词：

D O I：

10.1021/jo00131a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sun lamp illuminated alkoxycarbonylation of aryl, heteroaryl, and vinyl halides was performed under atmospheric pressure of CO in the presence of a cobalt catalyst in situ generated from Co(OAc)(2). Illumination through a Pyrex flask was sufficient to catalyze the reaction. This process avoids the use of Co-2(CO)(8) and excess CH3I, which were required in the earlier procedure. A S-RN(1) mechanism is proposed.

引用

页码：8336 / 8340

页数：5

共 25 条

[1] STEREOSPECIFIC NICKEL AND PHASE-TRANSFER CATALYZED CARBONYLATION OF VINYL BROMIDES AND CHLORIDES [J].