NEW TRIPHENYLGERMANIUM(IV) COMPLEXES OF N-PROTECTED AMINO-ACIDS - SYNTHETIC AND STRUCTURAL ASPECTS

被引：0

作者：

JAIN, A ^{[1
]}

SAXENA, S ^{[1
]}

RAI, AK ^{[1
]}

机构：

[1] UNIV RAJASTHAN, DEPT CHEM, JAIPUR 302004, RAJASTHAN, INDIA

来源：

MAIN GROUP METAL CHEMISTRY | 1994年 / 17卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Some triphenylgermanium (IV) complexes of general formula, [GRAPHICS] and -CHR- = -CH2CH2-) have been prepared by the reaction of triphenylgermanium(IV) chloride with the sodium salt of N-protected amino acids (LH), in 1:1 molar ratio in benzene solution. The structural considerations of these complexes are based upon physico-chemical and spectral studies. These derivatives are monomer in non-aqueous solution. The carboxylic group of the ligand is behaving as monodentate as inferred from IR and C-13 NMR.

引用

页码：641 / 647

页数：7

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