NEW TRIPHENYLGERMANIUM(IV) COMPLEXES OF N-PROTECTED AMINO-ACIDS - SYNTHETIC AND STRUCTURAL ASPECTS

被引：0
|
作者：
JAIN, A [1 ]
SAXENA, S [1 ]
RAI, AK [1 ]
机构：
[1] UNIV RAJASTHAN, DEPT CHEM, JAIPUR 302004, RAJASTHAN, INDIA
来源：
MAIN GROUP METAL CHEMISTRY | 1994年 / 17卷 / 09期
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Some triphenylgermanium (IV) complexes of general formula, [GRAPHICS] and -CHR- = -CH2CH2-) have been prepared by the reaction of triphenylgermanium(IV) chloride with the sodium salt of N-protected amino acids (LH), in 1:1 molar ratio in benzene solution. The structural considerations of these complexes are based upon physico-chemical and spectral studies. These derivatives are monomer in non-aqueous solution. The carboxylic group of the ligand is behaving as monodentate as inferred from IR and C-13 NMR.
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页码：641 / 647
页数：7
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