SYNTHESIS, CHARACTERIZATION AND FLUXIONAL BEHAVIOR OF [NI(ETA(5)-P(2)C(3)BU(3)(T))(ETA(3)-P(2)C(3)BU(3)(T))]

被引：21

作者：

CLOKE, FGN ^{[1
]}

FLOWER, KR ^{[1
]}

JONES, C ^{[1
]}

MATOS, RM ^{[1
]}

NIXON, JF ^{[1
]}

机构：

[1] UNIV FED MINAS GERAIS,ICEX,DEPT QUIM,BR-31270901 BELO HORIZONT,MG,BRAZIL

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

NICKEL; POLYPHOSPHOLYL LIGANDS; FLUXIONALITY; RING SLIPPAGE;

D O I：

10.1016/0022-328X(94)05128-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of either [Na(DME)(3)][P(2)C(3)Bu(3)(t)] or [Yb(P(2)C(3)Bu(3)(t))(2)] with [NiBr2(DME)(2)] affords the title compound which displays eta(5)-eta(3)-''ring slippage'' behaviour in solution.

引用

页码：C21 / C23

页数：3

共 50 条

[1] Di- and triphospha-ferrocenes: Crystal and molecular structures of [Fe(eta(5)-C(5)Me(5))(eta(5)-C(3)(t)Bu(3)P(2))] and of the adducts [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Mo(CO)(5)] and [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))W(CO)(5)]
Muller, C
Bartsch, R
Fischer, A
Jones, PG
Schmutzler, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 512 (1-2) : 141 - 148
[2] SYNTHESES AND P-31 NMR-STUDIES OF RUTHENIUM(II), RHODIUM(I), AND RHODIUM(III) COMPLEXES CONTAINING ETA(5)-P(2)C(3)(T)BU(3) AND ETA(5)- AND ETA(1)-P(3)C(2)(T)BU(2) LIGATED RING-SYSTEMS - CRYSTAL-STRUCTURES OF [RH(ETA(5)-P(2)C(3)(T)BU(3))(ETA(4)-COD)] (COD=1,5-CYCLOOCTADIENE) AND THE NOVEL HYDRIDO-ETA(1)-TRIPHOSPHACYCLOPENTADIENYL COMPLEX [RHH(ETA(1)-P(3)C(2)(T)BU(2))(ETA-5-C5ME5)PPH(3)]
HITCHCOCK, PB
MATOS, RM
NIXON, JF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) : 319 - 329
[3] PENTAPHOSPHA AND HEXAPHOSPHA FERROCENES AS LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF [FE(ETA-5-P3C2(T)BU2)2W(CO)5], [FE(ETA-5-P3C2(T)BU2)(ETA-5-P2C3(T)BU3)W(CO)5] AND THE NOVEL TRIRUTHENIUM CARBONYL CLUSTER COMPLEX [FE(ETA-5-P3C2(T)BU2)2RU3(CO)10] CONTAINING 2 INTERLINKED ETA-5-P3C2(T)BU2 RING-SYSTEMS
BARTSCH, R
GELESSUS, A
HITCHCOCK, PB
NIXON, JF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 430 (01) : C10 - C14
[4] Triphospha-ferrocenes as ligands. Crystal structures of [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))M(CO)(5))], (M=Cr,Mo,W) and the novel ruthenium and nickel complexes [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Ru-3(CO)(9)] and [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Ni(CO)(2)](2)
Bartsch, R
Muller, C
Fischer, A
Jones, PG
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 111 (1-4): : 684 - 684
[5] Remarkable 'edge' ligation of a triphosphacyclopentenyl ring system. Synthesis, crystal and molecular structure of [Ni(eta(5)-P3C2Bu2t){eta(2)-P3C2Bu2tCH(SiMe3)(2)Me}]
Caliman, V
Hitchcock, PB
Nixon, JF
CHEMICAL COMMUNICATIONS, 1997, (18) : 1739 - 1740
[6] The synthesis and structure of [Zr(eta-C5H5)(2)(eta(2)-C(5)H(3)Bu(2)(t))X]
Corradi, MM
Duncalf, DJ
Lawless, GA
Waugh, MP
CHEMICAL COMMUNICATIONS, 1997, (02) : 203 - 204
[7] Syntheses and structural characterisation of [Ir-4(CO)(11)(eta(1)-L)] and [Ir-4(CO)(10)(eta(1)-L)(2)] {L=[Fe(eta(5)-P(3)C(2)Bu(2)(t))(eta(5)-P(2)C(3)Bu(3)(t))] and [Fe(eta(5)-C5H5)(eta(5)-P(3)C(2)Bu(2)(t))]} and [Ir-4(CO)(11){mu-eta(1):eta(1)-[Fe(eta(5)-C5H5)(eta(5)-P(3)C(2)Bu(2)(t))]}Ir-4(CO)(11)] and its facile conversion to [Ir4H(CO)(10){Fe(eta(5)-C5H5)[eta(5)-P3C(CMe(2)CH(2))CBu(t)]}Ir-4(CO)(11)], via an unusual C-H activation
Benvenutti, MHA
Hitchcock, PB
Nixon, JF
Vargas, MD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (05): : 739 - 746
[8] SYNTHESIS, CRYSTAL AND MOLECULAR-STRUCTURE OF THE SLIPPED SANDWICH COMPLEX [NI(ETA-5-P3C2BUT2)(ETA-3-P2C3BUT3)]
BARTSCH, R
HITCHCOCK, PB
NIXON, JF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 373 (02) : C17 - C20
[9] Synthesis, structure, and properties of {((t)Bu(2)PC(2)H(4)P(t)Bu(2))Ni}(2)(mu-eta(2):eta(2)-C6H6) and ((t)Bu(2)PC(2)H(4)P(t)Bu(2))Ni(eta(2)-C6F6)
Bach, I
Porschke, KR
Goddard, R
Kopiske, C
Kruger, C
Rufinska, A
Seevogel, K
ORGANOMETALLICS, 1996, 15 (23) : 4959 - 4966
[10] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF AN UNUSUAL ETA(3)-LIGATED 1,3-DIPHOSPHACYCLOBUTADIENE MOLYBDENUM COMPLEX VIA CYCLODIMERIZATION OF A PHOSPHAALKYNE - CRYSTAL-STRUCTURE OF [MO(ETA(5)-C9H(7))(CO)(2)(P-ETA(3)-((T)BU)CPC((T)BU)PFBF3)]
HITCHCOCK, PB
MAAH, MJ
NIXON, JF
GREEN, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 466 (1-2) : 153 - 158

← 1 2 3 4 5 →