THEORETICAL-STUDY OF THE C3-PI-X3-PI TRANSITION IN CSI

被引:0
|
作者
TRINDER, W [1 ]
REINSCH, EA [1 ]
ROSMUS, P [1 ]
机构
[1] UNIV FRANKFURT,FACHBEREICH CHEM,D-60325 FRANKFURT,GERMANY
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 1993年 / 48卷 / 8-9期
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D O I
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The radiative lifetimes of the C3PI-X3PI transition of the CSi radical have been calculated from highly correlated electronic wavefunctions and compared with available experimental data. For this transition, the Franck-Condon approximation fails due to the strong R-dependency of the transition moment function.
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页码:895 / 898
页数:4
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