THE STANDARD GIBBS FREE-ENERGY OF ADSORPTION AND ISOTHERMS OF ADSORPTION OF AMPHIPHILIC MOLECULES AND CLUSTERS AT THE OIL-WATER AND GAS WATER INTERFACES - ADSORPTION OF DRY AND HYDRATED CHLOROPHYLL

被引：13
作者：
MARKIN, VS
GUGESHASHVILI, MI
VOLKOV, AG
MUNGER, G
LEBLANC, RM
机构：
[1] AN FRUMKIN ELECTROCHEM INST,MOSCOW 117071,USSR
[2] MICHIGAN STATE UNIV,DEPT HORT PLANT & SOIL SCI BLDG,E LANSING,MI 48824
[3] UNIV QUEBEC,CTR RECH PHOTOBIOPHYS,TROIS RIVIERES GA9 5H7,QUEBEC,CANADA
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1992年 / 154卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
D O I：
10.1016/0021-9797(92)90100-Z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The thermodynamics of adsorption of large surface active compounds at the interface between two immiscible liquids is considered. These molecules are supposed to substitute at the interface a number of adsorbed molecules of both solvents. Gibbs free energy and the isotherm of adsorption of surface active amphiphilic compounds were calculated. The adsorption isotherms of dry and wet chlorophyll a at the octane/water and air/water interfaces are measured. The difference between the adsorption behavior of chlorophyll a dissolved in dry and wet octane is discovered. The thermodynamic parameters of chlorophyll monomer and hydrated oligomer of chlorophyll a adsorption at octane/water interface are determined. © 1992.
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页码：264 / 275
页数：12
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