MASS-SPECTROMETRY OF MACROCYCLIC-COMPOUNDS

被引：6

作者：

KIREMIRE, B ^{[1
]}

SERAGLIA, R ^{[1
]}

TRALDI, P ^{[1
]}

机构：

[1] CNR,AREA RIC PADOVA,SERV SPETTROMET MASSA,I-35100 PADUA,ITALY

来源：

RAPID COMMUNICATIONS IN MASS SPECTROMETRY | 1991年 / 5卷 / 11期

关键词：

D O I：

10.1002/rcm.1290051112

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The mass spectrometric behaviour of more than 60 different macrocyclic compounds is reviewed in detail with the aim of depicting general fragmentation pathways, well-related to the different structural classes. In general, the electron-ionization-induced decomposition is characterized by the ejection of single molecules characteristic of the macrocycle. [M + H]+ and [M/2 + H]+ ions are always encountered due to the intrinsic basicity of such molecules.

引用

页码：543 / 556

页数：14

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