A NEW METHOD FOR THE INSITU GENERATION OF CP2ZR(H)CL (SCHWARTZ REAGENT)

被引:67
作者
LIPSHUTZ, BH
KEIL, R
ELLSWORTH, EL
机构
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0040-4039(00)88538-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Treatment of Cp2ZrCl2 with LiEt3BH in THF leads to formation of Cp2Zr(H)Cl. Subsequently introduced terminal acetylenes undergo hydrozirconation without compromising acid-sensitive functionality present in the alkyne. © 1990.
引用
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页码:7257 / 7260
页数:4
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