PALLADIUM-MEDIATED CYCLOPENTANATION OF ALKENES BEARING A NUCLEOPHILIC SUBSTITUENT - STEREOCHEMISTRY AND MECHANISM

被引：31

作者：

BOUYSSI, D

BALME, G

FOURNET, G

MONTEIRO, N

GORE, J

机构：

[1] Laboratoire de Chimie Organique 1, associé au CNRS, Université Claude Bernard, 69622 Villeurbanne, 43 Bd du

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(00)74293-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The increased facility of the reaction 1 --> 2 simultaneously with the increased nucleophilicity of the malonate, as well as the stereospecificity observed in the case of 3, led to the conclusion that the cyclisation proceeds by a nucleophilic attack on the double bond activated by a palladium(II) species.

引用

页码：1641 / 1644

页数：4

共 9 条

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FOURNET, G ;

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TETRAHEDRON LETTERS, 1989, 30 (01) :69-70

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[8] PALLADIUM-CATALYZED SYNTHESIS OF TRANS-2,5-DIARYLTETRAHYDROFURANS, POTENT PLATELET-ACTIVATING FACTOR ANTAGONISTS [J].

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