PALLADIUM-MEDIATED CYCLOPENTANATION OF ALKENES BEARING A NUCLEOPHILIC SUBSTITUENT - STEREOCHEMISTRY AND MECHANISM

被引：31
作者：
BOUYSSI, D
BALME, G
FOURNET, G
MONTEIRO, N
GORE, J
机构：
[1] Laboratoire de Chimie Organique 1, associé au CNRS, Université Claude Bernard, 69622 Villeurbanne, 43 Bd du
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 13期
关键词：
D O I：
10.1016/S0040-4039(00)74293-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The increased facility of the reaction 1 --> 2 simultaneously with the increased nucleophilicity of the malonate, as well as the stereospecificity observed in the case of 3, led to the conclusion that the cyclisation proceeds by a nucleophilic attack on the double bond activated by a palladium(II) species.
引用
收藏
页码：1641 / 1644
页数：4
相关论文
共 9 条
1