CRYSTAL-STRUCTURES AND BONDING IN NOCL, NO2CL, AND NO3CL

被引：23

作者：

OBERMEYER, A ^{[1
]}

BORRMANN, H ^{[1
]}

SIMON, A ^{[1
]}

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,D-70569 STUTTGART,GERMANY

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 30期

关键词：

D O I：

10.1021/ja00135a006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of NOCl, NO2Cl, and NO3Cl have been determined. NOCl forms a high-temperature phase (Cmcm, a = 413.2(1) pm, b = 1082.9(3) pm, c = 546.1(1) pm at -125 degrees C) with the NO moiety showing 2-fold disorder while in the low-temperature modification (Pnma, a = 1085.6(2) pm, b = 539.93(9) pm, c = 406.63(8) pm at -160 degrees C) continuous ordering is observed. The structure of the molecule is remarkably different in the solid state as compared to the gas phase. NO2Cl crystallizes in the triclinic system (P (1) over bar, a = 543.1(1) pm, b = 737.4(1) pm, c = 758.1(1) pm, alpha = 72.39(1)degrees, beta = 78.88(2)degrees, gamma = 89.56(2)degrees at -170 degrees C) with two crystallographically independent molecules in the asymmetric unit. NO3Cl is best described as an adduct of the radicals NO2 and ClO (P2(1)2(1)2(1), a = 385.6(1) pm, b = 675.5(2) pm, c = 1207.6(3) pm at -166 degrees C).

引用

页码：7887 / 7890

页数：4

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