CATALYTIC ACTIVITY OF COMPLEXES OF ALUMINUM HALIDES IN SOLID-PHASE HYDROCHLORINATION OF ETHYLENE

被引：0
|
作者：
ROSTOVSHCHIKOVA, TN
ZAGORSKAYA, OV
MUKHAMETOVA, LI
SMIRNOV, VV
机构：
来源：
KINETICS AND CATALYSIS | 1995年 / 36卷 / 01期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalytic activity of aluminum halides in the solid-phase reactions of ethylene with hydrogen chloride at 80 - 150 K is investigated by IR spectroscopy. It is shown that the interaction of aluminum bromide with HCl yields a mixed halide Al2Br2Cl4, which catalyzes the hydrochlorination of ethylene at 110 - 120 K. The formation of a complex of ethylene with MX(3) facilitates the oligomerization of ethylene.
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页码：137 / 141
页数：5
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