OXIDATIVE DECARBOXYLATION OF MANDELATE ETHERS AND ALPHA-SUBSTITUTED PHENYLACETATES VIA DIOXETANONE GENERATION

被引：8
作者：
HECKMANN, B
ALAYRAC, C
MIOSKOWSKI, C
CHANDRASEKHAR, S
FALCK, JR
机构：
[1] UNIV LOUIS PASTEUR,FAC PHARM,CNRS,SYNTHESE BIOORGAN LAB,74 ROUTE RHIN,F-67401 ILLKIRCH GRAFFENS,FRANCE
[2] UNIV TEXAS,SW MED CTR,DEPT MOLEC GENET & PHARMACOL,DALLAS,TX 75235
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 36期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0040-4039(00)79133-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Mandelate ethers are oxidatively decarboxylated via in situ generated dioxetanones using tBuOK and air at ambient temperature leading, after hydrolysis, to the benzoic acid and the corresponding alcohol. The reaction can be extended to alpha-substituted phenylacetates.
引用
收藏
页码：5205 / 5208
页数：4
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